Direct sum of irreducible representation
A' |
A'' |
17 |
0 |
Properties of derivatives and isotopomers by single substitution, h(Cs)=2
Atom Set* | Site Symmetry** | h(Site Symmetry) | Identical Atoms*** | Element | Chrial | Polar | Isotopomer |
---|
Isotope | Mass | Abundance**** |
---|
1 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
2 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
3 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
4 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
5 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
6 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
7 | Cs |
2 | 1 | N | no | yes | 15N | 130.0549 | 0.3310 |
8 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
9 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
10 | Cs |
2 | 1 | C | no | yes | 13C | 130.0612 | 1.0021 |
11 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
12 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
13 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
14 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
15 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
16 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
17 | Cs |
2 | 1 | H | no | yes | 2H | 130.0641 | 0.014057 |
Total Number of Atoms: | 17 | ✅ Correct Number of Atoms found |
*Atom Orbit
**Subgroup of point group C
s
***Calculated as h( C
s)/h(Site Symmetry)
****Natural Abundance of single substituted Isotopomer in %
Numbers of isomers by substitution
Replacement | Pattern | Achiral Isomers | Chiral Isomer Pairs |
Single | X | 17 | 0 |
Double | X2 | 136 | 0 |
Double | XY | 272 | 0 |
Triple | X3 | 680 | 0 |
Triple | X2Y | 2.040 | 0 |
Triple | XYZ | 4.080 | 0 |
Quadruple | X4 | 2.380 | 0 |
Quadruple | X3Y | 9.520 | 0 |
Quadruple | X2Y2 | 14.280 | 0 |
Quadruple | X2YZ | 28.560 | 0 |
Quadruple | WXYZ | 57.120 | 0 |
Quintuple | X5 | 6.188 | 0 |
Quintuple | VWXYZ | 742.560 | 0 |
Sextuple | X6 | 12.376 | 0 |
Sextuple | UVWXYZ | 8.910.720 | 0 |
Further Reading
- P.W. Fowler, J. Chem. Soc. Faraday Trans. 91(15) 2241 (1995)
Isomer Counting using Point Group Symmetry
Representation Γ3N
Characters of reducible representation
E |
σh |
51 |
17 |